Treatment of [(IPr)Pd(Cl)(2)(PR(2)H)] (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene; R = Cy, tBu, or 1-Ad) with NaN(SiMe(3))(2) generated isolable [(IPr)Pd(PR(2)Cl)] complexes (68-75%) that have been crystallographically characterized. The formation of these mixed-ligand Pd(0) species in this manner corresponds to an unusual net dehydrohalogenation/P-Cl reductive elimination sequence.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c1dt11910a | DOI Listing |
Publication Analysis
Top Keywords
[iprpdpr2cl] complexes
8
reductive elimination
8
generation [iprpdpr2cl]
4
complexes p-cl
4
p-cl reductive
4
elimination treatment
4
treatment [iprpdcl2pr2h]
4
[iprpdcl2pr2h] ipr
4
ipr 13-bis26-diisopropylphenylimidazol-2-ylidene
4
13-bis26-diisopropylphenylimidazol-2-ylidene tbu
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!