Cyclopentadiene and 1,3-cyclohexadiene are readily polymerised by [LAu][X]. With specific ancillary ligands polymerisation was suppressed and a molecular species involving an Au(I) cation η(2)-bonding CpH was isolated and whose structure was probed in both the solid state and in solution.
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| http://dx.doi.org/10.1039/c1cc16193h | DOI Listing |
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