A new rhodamine-based receptor, derivatized with an additional fluorophore (quinoline), was synthesized for selective recognition of Hg(2+) and Cr(3+) in an acetonitrile/HEPES buffer medium of pH 7.3. This reagent could be used as a dual probe and allowed detection of these two ions by monitoring changes in absorption and the fluorescence spectral pattern. In both instances, the extent of the changes was significant enough to allow visual detection. More importantly, the receptor molecule could be used as an imaging reagent for detection of Hg(2+) and Cr(3+) uptake in live human cancer cells (MCF7) using laser confocal microscopic studies. Unlike Hg(ClO(4))(2) or Hg(NO(3))(2) salts, HgCl(2) or HgI(2) failed to induce any visually detectable change in color or fluorescence upon interaction with L(1) under identical experimental conditions. Presumably, the higher covalent nature of Hg(II) in HgCl(2) or HgI(2) accounts for its lower acidity and its inability to open up the spirolactam ring of the reagent L(1). The issue has been addressed on the basis of the single-crystal X-ray structures of L(1)·HgX(2) (X(-) = Cl(-) or I(-)) and results from other spectral studies.
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http://dx.doi.org/10.1021/ic2017243 | DOI Listing |
Spectrochim Acta A Mol Biomol Spectrosc
December 2024
Department of Chemistry, School of Sciences, National Institute of Technology Andhra Pradesh, Tadepalligudem 534101, Andhra Pradesh, India. Electronic address:
Herein, we have used a simple synthetic strategy to access a novel non-sulfur fluorescent molecular probe coumarin and 1,8-napthyridine conjugated probe DNCS. The developed probe has great selectivity and sensitivity for detecting Hg ions. Our photophysical properties evaluation for the synthesized probe with different metal ions (Ba, Al, Ca, Bi, Ce, Cd, Cu, Sr, Co, Fe, Cr, Fe, Mn, Hg, Zn, Pb, Ni, and Sn) unveiled the very selective and sensitive fluorescence sensing behavior with Hg ions in the energy window of near UV and visible light radiation in an organic aqueous solvent mixture (EtOH and water).
View Article and Find Full Text PDFBeilstein J Nanotechnol
November 2024
Nanomaterial Toxicology Laboratory, Drug and Chemical Toxicology Group, Food, Drug and Chemical, Environment and Systems Toxicology (FEST) Divison, CSIR-Indian Institute of Toxicology Research (CSIR-IITR), Vishvigyan Bhawan, 31 Mahatma Gandhi Marg, Lucknow 226001, India.
Heavy metal ions and organic pollutants, such as 4-nitrophenol (4-NP), pose significant environmental and human health threats. Addressing these challenges necessitates using advanced nanoparticle-based systems capable of efficient detection and degradation. However, conventional approaches utilizing strong capping agents like cetrimonium bromide (CTAB) on nanoparticles lead to limitations due to the rigid nature of CTAB.
View Article and Find Full Text PDFRSC Adv
November 2024
Department of Pharmaceutical Chemistry, Faculty of Pharmacy, Mahidol University 447 Sri-Ayudhaya Rd., Rajathevee Bangkok 10400 Thailand
Distance-based detection (DbD) on paper-based microfluidic analytical devices (μPADs) has emerged as a promising, cost-effective, simple, and instrumentation-free assay method. Broadening the applicability of a new way of immobilization of reagent for DbD on μPADs (DμPADs) is presented, employing an ion exchange (IE) interaction of an anionic metallochromic reagent, 2-(5-bromo-2-pyridylazo)-5-[-propyl--(3-sulfopropyl)amino]phenol (5-Br-PAPS), on the anion-exchange filter paper. The IE DμPADs demonstrate superiority over standard cellulose filter paper in terms of the degree of reagent immobilization, detection sensitivity, and clear detection endpoints due to the strong retention of 5-Br-PAPS.
View Article and Find Full Text PDFFood Chem
January 2025
Beijing Laboratory of Food Quality and Safety, College of Food Science and Nutritional Engineering, China Agricultural University, Beijing 100083, China.. Electronic address:
Metal ions (MIs) identification is essential for the safety assessment, traceability and authentication of food. Most current approaches for detecting MIs are difficult to reconcile the simplicity, sensitivity and stability simultaneously. In this work, we proposed a novel strategy for discriminating MIs based on fluorescent supramolecular nanoaggregates (SNAs).
View Article and Find Full Text PDFDalton Trans
November 2024
Thammasat University Research Unit in Multifunctional Crystalline Materials and Applications (TU-MCMA), Faculty of Science and Technology, Thammasat University, Pathum Thani 12121, Thailand.
The solvothermal reactions of ZnCl·6HO, benzene-1,3,5-tribenzoic acid (Hbtb), and N-heterocyclic ancillary imidazole (Im) or aminopyrimidine (a mp) ligands led to the creation of two-dimensional (2D) zinc(II) based metal-organic frameworks (MOFs), (MeNH)[Zn(btb)(Im)]·2DMF·3MeOH (1) and (MeNH)[Zn(btb)(amp)]·HO·2DMF·MeOH (2). The btb ligands in 1 and 2 form an anionic 2D layered structure with a (6) honeycomb (hcb) topology by linking to Zn(II) centres through their carboxylate groups. The incorporation of N-heterocyclic auxiliary ligands Im and amp into the hcb nets resulted in the formation of a 2D hydrogen-bonded and covalently pillared bilayer structure featuring two-fold interpenetrating networks.
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