Synthesis of [(π-cyano-P-nacnac)Cp] and [(π-cyano-nacnac)Cp]-zirconium complexes, and their remote activation for ethylene polymerization.

Dalton Trans

Departamento de Química Inorgánica, Facultad de Química, Pontificia Universidad Católica de Chile, Casilla 306, Santiago-22, Chile.

Published: January 2012

In this contribution the synthesis and characterization of two distinct, yet similar, zirconium complexes, [(π-P-nacnac-CN)Cp] and [(π-nacnac-CN)Cp] zirconium dichloride were discussed. In addition to the complexes, Lewis acid adducts [B(C(6)F(5))(3)] of the complexes were isolated and characterized as well. It was found that while structurally similar, the complexes behave distinctly upon adduct formation and in their ethylene polymerizations.

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http://dx.doi.org/10.1039/c1dt11261aDOI Listing

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