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A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state. | LitMetric

A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state.

Chem Commun (Camb)

Ames Laboratory, US DOE and Department of Physics and Astronomy, Iowa State University, Ames, IA 50011, USA.

Published: January 2012

Ligand modification transforms a polyoxometalate-anchored cubane-type [Mn(III)(3)Mn(IV)O(4)] core into a centrosymmetric [Mn(III)(6)Mn(IV)O(8)] di-cubane cluster, and restores the slow magnetization relaxation characteristics typical for [Mn(4)O(4)] cubane-based single-molecule magnets.

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Source
http://dx.doi.org/10.1039/c1cc15520bDOI Listing

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