rac-Dimethyl [(9-anthr-yl)(4-methyl-anilino)meth-yl]phospho-nate.

Acta Crystallogr Sect E Struct Rep Online

Institute of Polymers, Bulgarian Academy of Sciences, Acad. G. Bonchev str., bl. 103A, 1113 Sofia, Bulgaria.

Published: August 2011

The title compound, C(24)H(24)NO(3)P, crystallizes as a racemate with two mol-ecules in the asymmetric unit. The structural features (bond lengths and angles) of the two mol-ecules are almost identical. The dihedral angle between the anthracene and toluidine rings is similar in the two mol-ecules, with values of 48.36 (9) and 51.15 (9)°. The methyl groups of one of the meth-oxy groups in one mol-ecule is disordered over two sets of sites, the major component having a site occupancy of 0.636 (3). In the crystal, both molecules are linked into inversion dimers by pairs of N-H⋯O hydrogen bonds.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213493PMC
http://dx.doi.org/10.1107/S1600536811027711DOI Listing

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rac-Dimethyl [(9-anthr-yl)(4-methyl-anilino)meth-yl]phospho-nate.

Acta Crystallogr Sect E Struct Rep Online

August 2011

Institute of Polymers, Bulgarian Academy of Sciences, Acad. G. Bonchev str., bl. 103A, 1113 Sofia, Bulgaria.

The title compound, C(24)H(24)NO(3)P, crystallizes as a racemate with two mol-ecules in the asymmetric unit. The structural features (bond lengths and angles) of the two mol-ecules are almost identical. The dihedral angle between the anthracene and toluidine rings is similar in the two mol-ecules, with values of 48.

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