In the title cationic Cp(*)Fe(II) complex, [Fe(C(10)H(15))(CH(3)CN)(C(14)H(16)NP)]PF(6)·C(4)H(8)O, the metal ion is coordinated by the η(5)-Cp* ring as well as the P and N atoms of the chelating 2-(diphenyl-phosphino)ethyl-amine ligand and an additional acetonitrile mol-ecule in a piano-chair conformation. The PF(6) (-) anion is disordered over two sets of sites with occupancies of 0.779 (7) and 0.221 (7).
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http://dx.doi.org/10.1107/S1600536811028832 | DOI Listing |
Acta Crystallogr E Crystallogr Commun
September 2019
Department of Chemistry, 875 Perimeter Dr. MS 2343 Moscow, ID 83844, USA.
The structure of the title complex, [Ag(CHNS)]PF, has monoclinic (2/) symmetry, and the silver atom has a distorted square-planar geometry. The coordination complex crystallized from mixing silver hexa-fluorido-phosphate with a concentrated tetra-hydro-furan solution of ,-di-ethyl-phenyl-azo-thio-formamide [ATF; systematic name: 3,3-diethyl-1-(phenyl-imino)-thio-urea] under ambient conditions. The resultant coordination complex exhibits a 2:1 ligand-to-metal ratio, with the silver(I) atom having a fourfold AgNS coordination sphere, with a single PF counter-ion.
View Article and Find Full Text PDFActa Crystallogr Sect E Struct Rep Online
August 2011
In the title cationic Cp(*)Fe(II) complex, [Fe(C(10)H(15))(CH(3)CN)(C(14)H(16)NP)]PF(6)·C(4)H(8)O, the metal ion is coordinated by the η(5)-Cp* ring as well as the P and N atoms of the chelating 2-(diphenyl-phosphino)ethyl-amine ligand and an additional acetonitrile mol-ecule in a piano-chair conformation. The PF(6) (-) anion is disordered over two sets of sites with occupancies of 0.779 (7) and 0.
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