[5-Chloro-2-hy-droxy-N'-(2-oxidobenzyl-idene)benzohydrazidato]dimethyl-tin(IV).

Acta Crystallogr Sect E Struct Rep Online

College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.

Published: August 2011

In the title compound, [Sn(CH(3))(2)(C(14)H(9)ClN(2)O(3))], the Sn(IV) ion is coordinated by one N and two O atoms from the tridentate 5-chloro-2-hy-droxy-N'-(2-oxidobenzyl-idene)benzohydrazidate (L) ligand and two methyl groups in a distorted trigonal-bipyramidal geometry. In the ligand, the hy-droxy group is involved in an intra-molecular O-H⋯N hydrogen bond and the two aromatic rings form a dihedral angle of 5.5 (1)°. In the crystal, weak inter-molecular C-H⋯O hydrogen bonds and π-π inter-actions between the aromatic rings [centroid-centroid distance = 3.816 (3) Å] link the mol-ecules into centrosymmetric dimers.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212120PMC
http://dx.doi.org/10.1107/S1600536811025621DOI Listing

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