Dichlorido(4'-ferrocenyl-2,2':6',2''-terpyridine-κN,N',N'')zinc acetonitrile monosolvate.

Acta Crystallogr Sect E Struct Rep Online

Key Laboratory of Functional Organometallic Materials, Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008, People's Republic of China.

Published: August 2011

The title complex, [FeZn(C(5)H(5))Cl(2)(C(20)H(14)N(3))]·CH(3)CN, is composed of one Zn(II) atom, one 4'-ferrocenyl-2,2':6',2''-terpyridine (fctpy) ligand, two Cl atoms and one acetonitrile solvent mol-ecule. The Zn(II) atom is five-coordinated in a trigonal-bipyramidal geometry by the tridentate chelating fctpy ligand and two Cl atoms.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3212113PMC
http://dx.doi.org/10.1107/S1600536811024950DOI Listing

Publication Analysis

Top Keywords

znii atom
8
fctpy ligand
8
ligand atoms
8
dichlorido4'-ferrocenyl-22'6'2''-terpyridine-κnn'n''zinc acetonitrile
4
acetonitrile monosolvate
4
monosolvate title
4
title complex
4
complex [feznc5h5cl2c20h14n3]·ch3cn
4
[feznc5h5cl2c20h14n3]·ch3cn composed
4
composed znii
4

Similar Publications

The title compound, [Zn(CHClNO)Cl], is a dinuclear zinc(II) complex with three chlorido ligands and one penta-dentate ligand containing quinolin-8-olato and bis-(pyridin-2-ylmeth-yl)amine groups. One of the two Zn atom adopts a tetra-hedral geometry and coordinates two chlorido ligands with chelate coord-ination of the N and O atoms of the quinolin-8-olato group in the ligand. The other Zn atom adopts a distorted trigonal-bipyramidal geometry, and coordinates one chlorido-O atom of the quinolin-8-olato group and three N atoms of the bis-(pyridin-2-ylmeth-yl)amine unit.

View Article and Find Full Text PDF

Herein, we describe a Zn-catalyzed atom-economical, inexpensive, and sustainable method for preparing a broad spectrum of substituted olefins utilizing alcohols as the main precursor. Using a Zn(II) complex [ZnLCl] () of the redox-noninnocent ligand 2-((4-chlorophenyl)diazenyl)-1,10-phenanthroline (), various ()-olefins were prepared in good yields by coupling alcohols with sulfones and aryl cyanides under an inert atmosphere. Under an aerial atmosphere, vinyl nitriles were isolated in up to 82% yield reacting alcohols with benzyl cyanides in the presence of .

View Article and Find Full Text PDF

New Cd(II), Zn(II), and Cu(II) chelates with cetirizine.2HCl (CETZ.2HCl) in incidence of 1,10 phenanthroline monohydrate (Phen.

View Article and Find Full Text PDF

Five metal dithiocarbamate complexes [M(PTHIQDTC)] [where PTHIQDTC is (S)-1-phenyl-1,2,3,4-tetrahydroisoquinoline dithiocarbamate anion and M is Ni(II) (1), Sn(II) (2), Hg(II) (3), Pb(II) (4) and Zn(II) (5)] were synthesized from the reaction of MX (X is Cl for 1-3 and OAc for 4-5) with ligand of triethylammonium (S)-1-phenyl-1,2,3,4-tetrahydroisoquinoline dithiocarbamate [EtNH][PTHIQDTC] in methanolic solution at room temperature. The five complexes were characterized by IR, H andC NMR, mass spectrometry, elemental analysis and TGA analysis. Recrystallization of [Zn(PTHIQDTC)] (5) in dimethylsulfoxide (DMSO) converts 5 to [Zn(PTHIQDTC)(DMSO)] (6).

View Article and Find Full Text PDF

Capture of trace benzene is an important and challenging task. Metal-organic framework materials are promising sorbents for a variety of gases, but their limited capacity towards benzene at low concentration remains unresolved. Here we report the adsorption of trace benzene by decorating a structural defect in MIL-125-defect with single-atom metal centres to afford MIL-125-X (X = Mn, Fe, Co, Ni, Cu, Zn; MIL-125, TiO(OH)(BDC) where HBDC is 1,4-benzenedicarboxylic acid).

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!