This study evaluated the vertical discrepancy of implant-fixed 3-unit structures. Frameworks were constructed with laser-sintered Co-Cr, and vacuum-cast Co-Cr, Ni-Cr-Ti, and Pd-Au. Samples of each alloy group were randomly luted in standard fashion using resin-modified glass-ionomer, self-adhesive, and acrylic/urethane-based cements (n = 12 each). Discrepancies were SEM analyzed. Three-way ANOVA and Student-Newman-Keuls tests were run (P < 0.05). Laser-sintered structures achieved the best fit per cement tested. Within each alloy group, resin-modified glass-ionomer and acrylic/urethane-based cements produced comparably lower discrepancies than the self-adhesive agent. The abutment position did not yield significant differences. All misfit values could be considered clinically acceptable.
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http://dx.doi.org/10.1007/s10266-011-0050-1 | DOI Listing |
J Phys Chem Lett
December 2024
School of Physical Science and Technology, Ningbo University, Ningbo 315211, China.
Triangular Au and tetrahedral Au are key structural units in the face-centered cubic gold core of thiolate-protected gold nanoclusters. Understanding their stacking arrangements is essential for elucidating the growth mechanisms of these gold cores. In this study, we design two new isomers of Au(SR) nanoclusters via deliberately adjusting the stacking pattern of Au and Au based on the grand unified model and ring model to show preferable packing arrangements.
View Article and Find Full Text PDFMolecules
November 2024
Center for Computational Quantum Chemistry, University of Georgia, Athens, GA 30602, USA.
Hericene is an unusual hexaolefin consisting of three 1,3-diene units located on a rigid bicyclo [2.2.2]octane framework that restricts the geometrical relationships of metal atoms bonded to these olefinic units.
View Article and Find Full Text PDFJ Phys Chem A
December 2024
Department of Chemistry, Anhui University, Hefei 230601, P. R. China.
Searching for a useful way to build stable hypercoordinate carbon species is a great way to enrich carbon-based chemical rules. Here, we extend the super valence bond model into superatom-atom superbonding to theoretically predict a two-dimensional (BCB)N monolayer, which is the first design of a stable nonplanar hexacoordinate carbon containing material, featuring a sandwich BCB configuration. Chemical bonding analyses indicate that its stability originates from the unique super CO structures, where each tricoordinate B unit has six delocalized electrons acting as a super oxygen (SP), and the BCB unit mimics the bonding pattern of the CO molecule via the superatom-atom super double bond.
View Article and Find Full Text PDFJ Pers Med
September 2024
Department of Prosthodontics Dental Therapy, Faculty of Dentistry, Necmettin Erbakan University, 42090 Konya, Turkey.
Background And Objectives: The aim of this study was to evaluate the influence of abutment angulation, types, and bone quality on fatigue performance in dental implant systems.
Materials And Methods: Three-dimensional models of maxillary 3-unit fixed implant-supported prostheses were analyzed. Abutments with different angles and types were used.
Inorg Chem
November 2024
School of Chemistry and Chemical Engineering, State Key Laboratory of Bio-fibers and Eco-textiles, Collaborative Innovation Center of Shandong Marine Bio-based Fibers and Ecological Textiles, Qingdao University, 308 NingXia Road, Qingdao 266071, P. R. China.
Atomically dispersed catalysts anchored on nitrogen-rich substrates present promising application potential for the persulfate-based advanced oxidation process. Nevertheless, efficient activation efficiency and a clear activated mechanism of persulfate remain challenging in carbon nitride-based single-atom catalysts (SACs). To these, combined with the regulation strategy of metal-ligand section and carrier's architecture, an atomically dispersed Co single-atom catalyst anchored on regular hollow tubular carbon nitride (Co/TCN SAC) herein was devised and utilized to activate permonosulfate.
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