Bis(hydrogen l-glutamato)palladium(II).

Acta Crystallogr Sect E Struct Rep Online

Institut für Chemie, Naturwissenschaftliche Fakultät II, Martin-Luther-Universität Halle-Wittenberg, Kurt-Mothes-Str. 2, 06120 Halle, Germany.

Published: October 2011

In the title compound, [Pd(C(5)H(8)NO(4))(2)], the Pd(II) atom is coordinated by two O atoms and two N atoms of two N,O-chelating hydrogen l-glutatmate ligands in a square-planar geometry with the N and O atoms in a mutually trans arrangement. The complex units are embedded in a network of N-H⋯O and O-H⋯O hydrogen-bonding inter-actions that stabilize the three-dimensional crystal structure. The strongest hydrogen bonds are formed between the γ-COOH untis of adjacent glutamate ligands, leading to dimers of the type R(2) (2)(8) with O⋯O separations of 2.640 (6) Å.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201544PMC
http://dx.doi.org/10.1107/S1600536811035860DOI Listing

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