AI Article Synopsis
- - The title compound features an Iridium (Ir) atom that is chelated by both acetyl-acetonate and 2-aryl-naphth[1,2-d]oxazole groups, forming a complex with a distorted octahedral geometry.
- - The compound includes intra-molecular C-H⋯O hydrogen bonds, which contribute to its structural stability.
- - In the crystal structure, inter-molecular C-H⋯O hydrogen bonds connect the molecules into columns that align parallel to the b axis, indicating organized stacking.
Article Abstract
In the title compound, [Ir(C(18)H(12)NO(2))(2)(C(5)H(7)O(2))], the Ir atom is O,O'-chelated by the acetyl-acetonate group and C,N-chelated by the 2-aryl-naphth[1,2-d]oxazole groups. The six-coordinate metal atom displays a distorted octa-hedral geometry. Intra-molecular C-H⋯O hydrogen bonds occur. In the crystal, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into columns parallel to the b axis.
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Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201473 | PMC |
| http://dx.doi.org/10.1107/S1600536811035690 | DOI Listing |
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