In the title compound, C(16)H(13)ClN(2)OS·H(2)O, the dihedral angle between the mean planes of the benzothia-zole ring system and the methylphenyl ring is 79.3 (6)°. The crystal packing features inter-molecular O-H⋯N, O-H⋯O and N-H⋯O hydrogen bonds involving the water mol-ecule and weak C-H⋯O, C-H⋯Cg and π-π stacking inter-actions [centroid-centroid distances = 3.8743 (7), 3.7229 (7) and 3.7076 (8) Å].

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201351PMC
http://dx.doi.org/10.1107/S1600536811035872DOI Listing

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