Poly[(μ(6)-6-oxidopyridinium-2-carboxyl-ato)caesium].

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, Chungnam National University, Daejeon 305-764, Republic of Korea.

Published: September 2011

The asymmetric unit of the polymeric title salt, [Cs(C(6)H(4)NO(3))](n), comprises a Cs(+) cation and a 6-oxidopyridinium-2-carboxyl-ate anion. The Cs(+) cation is six-coordinated by O atoms derived from two oxido and four carboxyl-ate O atoms; each O atom in the anion bridges two Cs(+) cations. In the crystal, inter-molecular N-H⋯O hydrogen bonding is present and contributes to the stability of the three-dimensional network generated by the bridging O atoms.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200864PMC
http://dx.doi.org/10.1107/S1600536811031874DOI Listing

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