The title compound, KSn(2)(PO(4))(3), belongs to the NASICON-type family of phosphates with the space group R[Formula: see text]. Its structure is constructed by very regular [with P-O distances ranging from 1.513 (6) to 1.522 (6) Å] PO(4) tetra-hedra and SnO(6) octa-hedra on the 3. axis, which are linked by O atoms, forming an [Sn(2)(PO(4))(3)] framework. The K atoms occupy the [Formula: see text]. axis sites and are located in the voids of this arrangement. The crystal studied was a merohedral twin with twin law (010 100 00[Formula: see text]) and a component ratio of 0.580 (7):0.420 (7).
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| http://dx.doi.org/10.1107/S1600536811035604 | DOI Listing |
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Potassium ditin(IV) tris-[phosphate(V)], KSn(2)(PO(4))(3).
Acta Crystallogr Sect E Struct Rep Online
October 2011
Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, People's Republic of China.
The title compound, KSn(2)(PO(4))(3), belongs to the NASICON-type family of phosphates with the space group R[Formula: see text]. Its structure is constructed by very regular [with P-O distances ranging from 1.513 (6) to 1.
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