4,10-Bis(pyridin-2-ylmeth-yl)-1,7-dithia-4,10-diazo-niacyclo-dodecane bis(perchlorate).

Acta Crystallogr Sect E Struct Rep Online

Department of Chemistry, Nanchang University, Nanchang 330031, People's Republic of China.

Published: September 2011

The asymmetric unit of the title compound C(20)H(30)N(4)S(2) (+). 2ClO(4) (-) comprises one macrocyclic cation and two perchlorate anions. In the cation, one of the protonated H atoms bound to the amide N atom is involved in an intra-molecular N-H⋯N hydrogen bond. The O atoms in the two perchlorate anions are disordered over two sets of sites with occupancy ratios of 0.65 (3):0.35 (3) and 0.640 (15):0.360 (15).

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200833PMC
http://dx.doi.org/10.1107/S1600536811032715DOI Listing

Publication Analysis

Top Keywords

perchlorate anions
8
410-bispyridin-2-ylmeth-yl-17-dithia-410-diazo-niacyclo-dodecane bisperchlorate
4
bisperchlorate asymmetric
4
asymmetric unit
4
unit title
4
title compound
4
compound c20h30n4s2
4
c20h30n4s2 2clo4
4
2clo4 comprises
4
comprises macrocyclic
4

Similar Publications

This review highlights recent advancements and challenges in fluorescence-based chemical sensors for selective and sensitive detection of perchlorate, a persistent environmental pollutant and global concern due to its health and safety implications. Perchlorate is a highly persistent inorganic pollutant found in drinking water, soil, and air, with known endocrine-disruptive properties due to its interference with iodide uptake by the thyroid gland. Human exposure mainly occurs through contaminated water and food.

View Article and Find Full Text PDF

Synthesis, crystal structure and properties of μ-tetra-thio-anti-monato-bis-[(cyclam)zinc(II)] perchlorate 0.8-hydrate.

Acta Crystallogr E Crystallogr Commun

October 2024

Institut für Anorganische Chemie, Universität Kiel, Max-Eyth.-Str. 2, D-24118 Kiel, Germany.

The reaction of Zn(ClO)·6HO with NaSbS·9HO in a water/aceto-nitrile mixture leads to the formation of the title compound, (μ-tetra-thio-anti-monato-κ :')bis-[(1,4,8,11-tetra-aza-cyclo-tetra-decane-κ )zinc(II)] perchlorate 0.8-hydrate, [Zn(SbS)(CHN)]ClO·0.8HO or [(Zn-cyclam)(SbS)][ClO]·0.

View Article and Find Full Text PDF

Four new and one previously reported silver 4,4'-vinylenedipyridine (Vpe) coordination polymers were tested as anion exchange materials to assess their potential for pollutant sequestration and compared to analogous silver 4,4'-bipyridine (bipy) coordination polymers. The materials were synthesized using nitrate, tetrafluoroborate, perchlorate, perrhenate, or chromate as the anion to produce cationic coordination polymers with solubilities ranging from 0.0137(7) to 0.

View Article and Find Full Text PDF

Extensive carbonate precipitation has occurred on Mars. To gain insight into the carbonation mechanisms and formation processes under ancient Martian aqueous conditions, we examine the precipitation of carbonates resulting from atmospheric carbon fixation, focusing on interactions between various brines and silicate and perchlorate solutions in alkaline environments. The micro-scale morphology and composition of the resulting precipitates are analysed using ESEM micrographs, EDX chemical compositional analysis, X-ray diffraction, and micro-Raman spectroscopy.

View Article and Find Full Text PDF

The synthesis and characterization of a novel bis-urea-based cage receptor for anions (3S,15S)-3,15,20,25-tetramethyl-1,4,6,12,14,17,20,25-octaazatricyclo[15.5.5.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!