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Dichlorido{2-[(thio-phen-2-ylmeth-yl)imino-meth-yl]pyridine-κN,N'}palladium(II). | LitMetric

Dichlorido{2-[(thio-phen-2-ylmeth-yl)imino-meth-yl]pyridine-κN,N'}palladium(II).

Acta Crystallogr Sect E Struct Rep Online

University of the Western Cape, Cape Town, Bellville 7535, South Africa.

Published: October 2011

In the title compound, [PdCl(2)(C(11)H(10)N(2)S)], the Pd(II) ion is four-coordinated in a distorted square-planar environment by two N atoms of the chelating 2-[(thio-phen-2-ylmeth-yl)imino-meth-yl]pyridine ligand and two chloride anions. The thio-phene ring is rotationally disordered over two orientations in a 1:1 ratio. The crystal packing exhibits weak inter-molecular C-H⋯Cl and C-H⋯S hydrogen bonds.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201550PMC
http://dx.doi.org/10.1107/S1600536811037214DOI Listing

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