Stark broadened emission spectra, once separated from other broadening effects, provide a convenient non-perturbing means of making plasma density measurements. A deconvolution technique has been developed to measure plasma densities in the ZaP flow Z-pinch experiment. The ZaP experiment uses sheared flow to mitigate MHD instabilities. The pinches exhibit Stark broadened emission spectra, which are captured at 20 locations using a multi-chord spectroscopic system. Spectra that are time- and chord-integrated are well approximated by a Voigt function. The proposed method simultaneously resolves plasma electron density and ion temperature by deconvolving the spectral Voigt profile into constituent functions: a Gaussian function associated with instrument effects and Doppler broadening by temperature; and a Lorentzian function associated with Stark broadening by electron density. The method uses analytic Fourier transforms of the constituent functions to fit the Voigt profile in the Fourier domain. The method is discussed and compared to a basic least-squares fit. The Fourier transform fitting routine requires fewer fitting parameters and shows promise in being less susceptible to instrumental noise and to contamination from neighboring spectral lines. The method is evaluated and tested using simulated lines and is applied to experimental data for the 229.69 nm C III line from multiple chords to determine plasma density and temperature across the diameter of the pinch. These measurements are used to gain a better understanding of Z-pinch equilibria.
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Nat Genet
December 2024
Research Service, VA Northeast Ohio Healthcare System, Cleveland, OH, USA.
Eur J Pharm Biopharm
December 2024
Physical Medicine and Rehabilitation Department, Iran University of Medical Sciences, Tehran, Iran.
Pharmaceutical tablets need to have a homogenous chemical structure, especially in cases where the patient may divide the tablet in half prior to consumption. This work aims to demonstrate the viability of using laser induced breakdown spectroscopy (LIBS) for analyzing the homogeneity and determining the chemical composition of losartan potassium tablets. This was accomplished by obtaining the spectra of 10 tablet points in 30 successive laser pulses, which revealed four main peaks (C, H, N, and O) as well as a high concentration of calcium and potassium in the core tablets and titanium in the coating-all of which are excellent analytical objectives for LIBS.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
February 2025
Rare Earth College, Jiangxi University of Science and Technology, Ganzhou, Jiangxi 341000, China; National Rare Earth Functional Material Innovation Center, Ganzhou, Jiangxi 341000, China; Key Laboratory of Rare Earths, Chinese Academy of Sciences, Ganzhou, Jiangxi Province 341119, China. Electronic address:
Er-doped glasses and fibers with broadband near infrared (NIR) emission have been widely applied in EDFA. Limited by optical gain band of Er-doped glasses and fibers, it was hardly meet to the demands of broadband amplification in the C + L band. In this work, six glass matrixes were employed for discussing the influence of glass matrix on the Stark splitting of Er and the wavelength of laser output and amplification.
View Article and Find Full Text PDFAdv Sci (Weinh)
November 2024
Laboratory for Shock Wave and Detonation Physics, Institute of Fluid Physics, China Academy of Engineering Physics, Mianyang, 621900, China.
The concept of ferroelectric polarons is proposed to partially explain the exceptional optoelectronic properties observed in lead halide perovskites (LHPs). It is intriguing but unclear how this proposal, which involves local or transient polarizations, applies in general to 2D LHPs with long-range ferroelectricity. Here, this work presents a pioneering time-domain experimental investigation of polarons in ferroelectric (IA)(MA)PbBr (IMPB; IA is isoamylammonium and MA is methylammonium) using transient absorption spectroscopy.
View Article and Find Full Text PDFPLoS One
September 2024
Research Center for Advanced Materials Science (RCAMS), King Khalid University, Abha, Saudi Arabia.
One of the most significant medicinal plants used to treat numerous illnesses is Swertia chirayita. The present study demonstrated the compositional analysis of the Swertia chirayita (S. chirayita) plant using an emerging and non-destructive laser-induced breakdown spectroscopy (LIBS) technique.
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