Linear polystyrene-stabilized PdO nanoparticle-catalyzed Mizoroki-Heck reactions in water.

Molecules

Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi, Osaka, Japan.

Published: October 2011

AI Article Synopsis

  • Linear polystyrene-stabilized PdO nanoparticles (PS-PdONPs) were created by heating palladium acetate in a polystyrene environment.
  • X-ray diffraction and transmission electron microscopy confirmed the successful creation of these nanoparticles.
  • The PS-PdONPs showed excellent catalytic performance in Mizoroki-Heck reactions in water and could be reused multiple times without losing effectiveness.

Article Abstract

Linear polystyrene-stabilized PdO nanoparticles (PS-PdONPs) were prepared by thermal decomposition of Pd(OAc)(2) in the presence of polystyrene. X-ray diffraction (XRD) and transmission electron microscopy (TEM) indicated the production of PdO nanoparticles. The loading of palladium was determined by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). PS-PdONPs exhibited high catalytic activity for Mizoroki-Heck reactions under air in water and could be recycled without loss of activity.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6264568PMC
http://dx.doi.org/10.3390/molecules16119067DOI Listing

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