The structure of ordered mesoporous materials presenting a cubic structure undergoes a strong modification after adding aluminium alkoxides to the synthesis gel. As a result, an outstanding increase in the surface area and pore volume is observed, together with changes in the mesopore ordering. Hydrated aluminium species influence the chemical environment of the micelles during synthesis, which seems to induce the accumulation of stacking faults in the mesopore framework, and give rise to closer structural packing. The adsorption and release of ibuprofen as a test molecule correlates well with the textural changes observed.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c1cc15899fDOI Listing

Publication Analysis

Top Keywords

increase surface
8
surface area
8
ordered mesoporous
8
cubic structure
8
al-promoted increase
4
area adsorption
4
adsorption capacity
4
capacity ordered
4
mesoporous silica
4
silica materials
4

Similar Publications

Biomedical datasets are the mainstays of computational biology and health informatics projects, and can be found on multiple data platforms online or obtained from wet-lab biologists and physicians. The quality and the trustworthiness of these datasets, however, can sometimes be poor, producing bad results in turn, which can harm patients and data subjects. To address this problem, policy-makers, researchers, and consortia have proposed diverse regulations, guidelines, and scores to assess the quality and increase the reliability of datasets.

View Article and Find Full Text PDF

Background: Treatment of deep carious lesions poses significant challenges in dentistry, as complete lesion removal risks compromising pulp vitality, while selective removal often reduces the longevity of restorations. Herein, we propose a minimally invasive approach using High-Intensity Focused Ultrasound (HIFU) for microscale removal of carious dentine. Concurrently, HIFU's antimicrobial effects against associated cariogenic biofilms and the corresponding thermal and biological impacts on surrounding tissues were investigated.

View Article and Find Full Text PDF

Background: Motion complexity is necessary for adapting to external changes, but little is known about trunk motion complexity during seated perturbation in individuals with spinal cord injury (SCI). We aimed to investigate changes following SCI in trunk segmental motion complexity across different perturbation directions and how they affect postural control ability in individuals with SCI.

Methods: A total of 17 individuals with SCI and 18 healthy controls participated in challenging sagittal-seated perturbations with hand protection.

View Article and Find Full Text PDF

Piezoelectric materials directly convert between electrical and mechanical energies. They are used as transducers in applications such as nano-positioning and ultrasound imaging. Improving the properties of these devices requires piezoelectric materials capable of delivering a large longitudinal strain on the application of an electric field.

View Article and Find Full Text PDF

This in vitro study aims to evaluate various surface treatments on the shear bond strength and failure mode of CAD/CAM PMMA teeth to the heat-polymerized acrylic denture base. The study sample consisted of 100 teeth that were divided equally into five groups: Group 1: denture artificial teeth (control), Group 2: PMMA teeth without surface treatment, Group 3: PMMA teeth with MMA etching, Group 4: PMMA teeth with sandblasting (aluminum oxide particles), and Group 5: PMMA teeth with perpendicular grooves. The shear bond strength test was performed using a universal testing machine and the failure mode was recorded.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!