This communication reveals an innovative and facile procedure to prepare quinoxalines in two synthetic steps. The microwave assisted Petasis reaction is followed by the acid mediated unmasking of an internal amino nucleophile, cyclodehydration and oxidation to give collections of quinoxalines in good to excellent yields.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3189012 | PMC |
http://dx.doi.org/10.1016/j.tetlet.2011.06.115 | DOI Listing |
J Vis Exp
January 2025
Center for Gender-Specific Medicine, Istituto Superiore di Sanità.
Transgender (TG) people are individuals whose gender identity and sex assigned at birth do not match. They often undergo gender-affirming hormone therapy (GAHT), a medical intervention that allows the acquisition of secondary sex characteristics more aligned with their individual gender identity, providing consistent results in the improvement of numerous socio-psychological variables. However, GAHT targets different body systems, and some side effects are recorded, although not yet fully identified and characterized.
View Article and Find Full Text PDFFront Vet Sci
January 2025
Department of Veterinary Medicine, College of Agriculture and Veterinary Medicine, United Arab Emirates University, Al Ain, United Arab Emirates.
The current study performed a comprehensive assessment of blood supply in the cerebellum of dromedary camels. To the best of our knowledge, this study is the first to provide detailed information about the origins, routes, and complicated patterns of branching in the rostral and caudal cerebellar arteries of dromedary camels. In total, 55 heads from male dromedary camels aged 2-6 years were analyzed using advanced casting techniques.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Department of Physical Sciences, Chemistry Division, College of Science, Jazan University, P.O. Box. 114, Jazan 45142, Kingdom of Saudi Arabia.
Herein, electrochemical sensing of paracetamol in polluted water was achieved using facile-synthesized tungsten oxide nanoparticles. Ion exchange resin has been used as a sustainable preparation route, while the prepared nanoparticles have been characterized by XRD and SEM analyses. Orthorhombic WO·HO nano-plates have been synthesized a facile preparation method, where the crystal size has been calculated as 25-33 nm, and these results were used to create a 3D model of the prepared WO·HO nano-plates.
View Article and Find Full Text PDFWe analyze the single-photon band structure and the transport of a single photon in a one-dimensional coupled-spinning-resonator chain. The time-reversal symmetry of the resonators chain is broken by the spinning of the resonators, instead of external or synthetic magnetic field. Two nonreciprocal single-photon band gaps can be obtained in the coupled-spinning-resonator chain, whose width depends on the angular velocity of the spinning resonator.
View Article and Find Full Text PDFBMC Public Health
January 2025
Advanced Wellbeing Research Centre, Sheffield Hallam University, Sheffield, UK.
Background: Workplace health screening rarely includes measures of cardiorespiratory fitness, despite it being a greater predictor of cardiovascular disease and all-cause mortality than other routinely measured risk factors. This study aimed to determine the comparative acceptability of using a novel seismocardiography device to measure cardiorespiratory fitness via VO max during a workplace health check.
Methods: Participants were invited to participate in workplace health screening sessions where VO max was assessed by both seismocardiography at rest and sub-maximal exercise testing, in order for acceptability of both to be compared across multiple domains.
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