Phenothiazine derivatives with various conjugated linkers (furan, thiophene, and 3,4-ethylenedioxythiophene) were synthesized and used in dye-sensitized solar cells to study the effect of conjugated linkers on device performance. Among them, one with furan as a conjugated linker showed a solar energy-to-electricity conversion efficiency (η) of 6.58%, an improvement of over 24% compared with the T2-1 reference cells' 5.29% under AM 1.5 G irradiation.
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Spectrochim Acta A Mol Biomol Spectrosc
December 2024
Department of Chemistry, Faculty of Science, Al-Azhar University, Nasr City, Cairo 11884, Egypt. Electronic address:
The quick and precise estimation of D-π-A Organic Dye absorption maxima in different solvents is an important challenge for the efficient design of novel chemical structures that could improve the performance of dye-sensitized solar cells (DSSCs) and related technologies. Time-Dependent Density Functional Theory (TD-DFT) has often been employed for these predictions, but it has limitations, including high computing costs and functional dependence, particularly for solvent interactions. In this study, we introduce a high-accuracy and rapid deep-learning ensemble method using daylight fingerprints as chemical descriptors to predict the absorption maxima (λ) of D-π-A organic dyes in 18 different solvent environments.
View Article and Find Full Text PDFDalton Trans
December 2024
Energy Materials Laboratory, Chemistry, School of Natural and Environmental Sciences, Newcastle University, Newcastle upon Tyne, NE1 7RU, UK.
This article reports the development of CuO|CuBiO photocathodes stabilized by protective layers of TiO, MgO, or NiO, with Pt or MoS nanoparticles serving as co-catalysts to facilitate H evolution. Most notably, this work demonstrates the first application of MgO as a protection/passivation layer for photocathodes in a water-splitting cell. All configurations of photocathodes were studied structurally, morphologically, and photoelectrochemically revealing that CuO|CuBiO|MgO|Pt photocathodes achieve the highest stable photocurrent densities of -200 μA cm for over 3 hours with a Faradaic efficiency of ∼90%.
View Article and Find Full Text PDFBeilstein J Org Chem
November 2024
School of Chemistry and Forensic Science, University of Kent, Canterbury, CT2 7NH, UK.
Heliyon
November 2024
Department of Mechanical and Materials Engineering, Lee Kong Chian Faculty of Engineering and Science, Universiti Tunku Abdul Rahman, Sungai Long Campus, Bandar Sungai Long, 43000, Kajang, Malaysia.
Considering global climate change concerns, issues related to the energy crisis and technologies reliant on non-fossil renewable energy sources are in high demand. Solar energy emerges as one of the alternatives among all renewable energy resources due to its economic viability and environmental sustainability. There are various types of solar photovoltaic (PV) technologies available for commercial applications, such as organic solar cells, silicon-based solar cells, dye-sensitized solar cells, and perovskite solar cells.
View Article and Find Full Text PDFNanotechnology
December 2024
Department of Applied Physics and Chemistry, University of Taipei, Taipei 10048, Taiwan.
Nitrogen-doped carbon dots (N-CDs) and vertically-grown tin disulfide (SnS) nanosheets are synthesized via hydrothermal method and chemical vapor deposition technique, respectively. The SnSnanosheets are directly fabricated on flexible carbon cloth (CC), and then their basal planes are decorated with N-CDs. The as-prepared composite electrodes are used as the counter electrode for the application in dye-sensitized solar cells (DSSCs).
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