Raman characterization of ABA- and ABC-stacked trilayer graphene.

ACS Nano

Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore.

Published: November 2011

Bernal (ABA stacking order) and rhombohedral (ABC) trilayer graphene (3LG) are characterized by Raman spectroscopy. From a systematic experimental and theoretical analysis of the Raman modes in both of these 3LGs, we show that the G band, G' (2D) band, and the intermediate-frequency combination modes of 3LGs are sensitive to the stacking order of 3LG. The phonon wavevector q, that gives the double resonance Raman spectra is larger in ABC than ABA, which is the reason why we get the different Raman frequencies and their spectral widths for ABA and ABC 3LG. The weak electron-phonon interaction in ABC-stacked 3LG and the localized strain at the boundary between ABC- and ABA-stacked domains are clearly reflected by the softening of the G mode and the G' mode, respectively.

Download full-text PDF

Source
http://dx.doi.org/10.1021/nn203472fDOI Listing

Publication Analysis

Top Keywords

trilayer graphene
8
stacking order
8
modes 3lgs
8
raman
5
raman characterization
4
characterization aba-
4
aba- abc-stacked
4
abc-stacked trilayer
4
graphene bernal
4
bernal aba
4

Similar Publications

Electronic ferroelectricity in monolayer graphene moiré superlattices.

Nat Commun

December 2024

Key Laboratory for Quantum Materials of Zhejiang Province, Department of Physics, School of Science, Westlake University, 18 Shilongshan Road, Hangzhou, 310024, Zhejiang Province, China.

Extending ferroelectric materials to two-dimensional limit provides versatile applications for the development of next-generation nonvolatile devices. Conventional ferroelectricity requires materials consisting of at least two constituent elements associated with polar crystalline structures. Monolayer graphene as an elementary two-dimensional material unlikely exhibits ferroelectric order due to its highly centrosymmetric hexagonal lattices.

View Article and Find Full Text PDF

Layer-dependent evolution of electronic structures and correlations in rhombohedral multilayer graphene.

Nat Nanotechnol

November 2024

Key Laboratory for Micro/Nano Optoelectronic Devices of Ministry of Education and Hunan Provincial Key Laboratory of Low-Dimensional Structural Physics and Devices, School of Physics and Electronics, Hunan University, Changsha, China.

Article Synopsis
  • Recent research on trilayer rhombohedral graphene (RG) reveals its potential for studying strong correlation electronic phenomena due to observed superconductivity and magnetism.
  • The study uncovers layer-dependent electronic structures in RG multilayers ranging from 3 to 9 layers, highlighting enhanced low-energy flat bands and varying interlayer interactions at liquid nitrogen temperatures.
  • Findings show significant splittings of these flat bands, indicating the emergence of strongly correlated states, with the strongest correlations found in six-layer RG, validating theoretical predictions and suggesting RG as a promising platform for further research.
View Article and Find Full Text PDF

Suppression of symmetry-breaking correlated insulators in a rhombohedral trilayer graphene superlattice.

Nat Commun

November 2024

State Key Laboratory for Mesoscopic Physics, School of Physics, Peking University, Beijing, 100871, China.

Counterintuitive temperature dependence of isospin flavor polarization has recently been found in twisted bilayer graphene, where unpolarized electrons in a Fermi liquid become a spin-valley polarized insulator upon heating. So far, the effect has been limited to v = +/-1 (one electron/hole per superlattice cell), leaving open questions such as whether it is a general property of symmetry-breaking electronic phases. Here, by studying a rhombohedral trilayer graphene/boron nitride moiré superlattice, we report that at v = -3 a resistive peak emerges at elevated temperatures or in parallel magnetic fields.

View Article and Find Full Text PDF

Unconventional Discontinuous Transitions in Isospin Systems.

Phys Rev Lett

October 2024

School of Physics and Astronomy and William I. Fine Theoretical Physics Institute, University of Minnesota, Minneapolis, Minnesota 55455, USA.

We show that two-dimensional fermions with dispersion k^{2} or k^{4} undergo a first-order Stoner transition to a fully spin-polarized state despite the fact that the spin susceptibility diverges at the critical point. We extend our analysis to systems with dispersion k^{2α} and spin and valley isospin and show that there is a cascade of instabilities into fractional-metal states with some electron bands fully depleted; narrow intermediate ranges of partially depleted bands exist for α<1 or α>2. The susceptibility becomes large near each transition.

View Article and Find Full Text PDF
Article Synopsis
  • Fractional quantum Hall (FQH) phases involve strong electronic interactions producing anyonic quasiparticles with unique properties, while integer quantum Hall (IQH) effects arise from the band topology of non-interacting electrons.* -
  • Our research reveals unexpected "super-universality" in the critical behavior of FQH and IQH transitions, where both types exhibit the same critical scaling exponent (κ = 0.41 ± 0.02) and localization length exponent (γ = 2.4 ± 0.2).* -
  • Using ultra-high mobility trilayer graphene devices, we demonstrate that these consistent critical exponents can be observed with short-range disorder, unlike previous studies that showed variability in conventional
View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!