Bernal (ABA stacking order) and rhombohedral (ABC) trilayer graphene (3LG) are characterized by Raman spectroscopy. From a systematic experimental and theoretical analysis of the Raman modes in both of these 3LGs, we show that the G band, G' (2D) band, and the intermediate-frequency combination modes of 3LGs are sensitive to the stacking order of 3LG. The phonon wavevector q, that gives the double resonance Raman spectra is larger in ABC than ABA, which is the reason why we get the different Raman frequencies and their spectral widths for ABA and ABC 3LG. The weak electron-phonon interaction in ABC-stacked 3LG and the localized strain at the boundary between ABC- and ABA-stacked domains are clearly reflected by the softening of the G mode and the G' mode, respectively.
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Nat Commun
December 2024
Key Laboratory for Quantum Materials of Zhejiang Province, Department of Physics, School of Science, Westlake University, 18 Shilongshan Road, Hangzhou, 310024, Zhejiang Province, China.
Extending ferroelectric materials to two-dimensional limit provides versatile applications for the development of next-generation nonvolatile devices. Conventional ferroelectricity requires materials consisting of at least two constituent elements associated with polar crystalline structures. Monolayer graphene as an elementary two-dimensional material unlikely exhibits ferroelectric order due to its highly centrosymmetric hexagonal lattices.
View Article and Find Full Text PDFNat Nanotechnol
November 2024
Key Laboratory for Micro/Nano Optoelectronic Devices of Ministry of Education and Hunan Provincial Key Laboratory of Low-Dimensional Structural Physics and Devices, School of Physics and Electronics, Hunan University, Changsha, China.
Nat Commun
November 2024
State Key Laboratory for Mesoscopic Physics, School of Physics, Peking University, Beijing, 100871, China.
Counterintuitive temperature dependence of isospin flavor polarization has recently been found in twisted bilayer graphene, where unpolarized electrons in a Fermi liquid become a spin-valley polarized insulator upon heating. So far, the effect has been limited to v = +/-1 (one electron/hole per superlattice cell), leaving open questions such as whether it is a general property of symmetry-breaking electronic phases. Here, by studying a rhombohedral trilayer graphene/boron nitride moiré superlattice, we report that at v = -3 a resistive peak emerges at elevated temperatures or in parallel magnetic fields.
View Article and Find Full Text PDFPhys Rev Lett
October 2024
School of Physics and Astronomy and William I. Fine Theoretical Physics Institute, University of Minnesota, Minneapolis, Minnesota 55455, USA.
We show that two-dimensional fermions with dispersion k^{2} or k^{4} undergo a first-order Stoner transition to a fully spin-polarized state despite the fact that the spin susceptibility diverges at the critical point. We extend our analysis to systems with dispersion k^{2α} and spin and valley isospin and show that there is a cascade of instabilities into fractional-metal states with some electron bands fully depleted; narrow intermediate ranges of partially depleted bands exist for α<1 or α>2. The susceptibility becomes large near each transition.
View Article and Find Full Text PDFNat Commun
October 2024
Department of Physics, Indian Institute of Science, Bangalore, 560012, India.
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