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http://dx.doi.org/10.1002/adma.201102875 | DOI Listing |
ACS Phys Chem Au
January 2025
Instituto de Ciência e Tecnologia, Universidade Federal de São Paulo, São José dos Campos, 12247-014 São Paulo, Brazil.
The unique properties and versatile applications of natural deep eutectic solvents (NaDES) have sparked significant interest in the field of green chemistry. Comprised of natural components that form liquids at room temperature through strong noncovalent electrostatic interaction, these solvents are cost-effective, nontoxic, and versatile. Betaine chloride-based NaDES, in particular, have shown promise in biocatalysis and sugar extraction due to their excellent properties.
View Article and Find Full Text PDFMater Today Bio
February 2025
China Uruguay Bio-Nano Pharmaceutical Joint Laboratory, Institute of Neuroregeneration and Neurorehabilitation, Qingdao University, 308 Ningxia Road, Qingdao, 266071, Shandong, China.
Well-designed artificial scaffolds are urgently needed due to the limited self-repair capacity of bone, which hampers effective regeneration in critical defects. Optimal scaffolds must provide physical guidance to recruit cells and immune regulation to improve the regenerative microenvironment. This study presents a novel scaffold composed of dual-sided centripetal microgrooved poly(D,L-lactide-co-caprolactone) (PLCL) film combined with a dynamic hydrogel containing prednisolone (PLS)-loaded Prussian blue nanoparticles (PB@PLS).
View Article and Find Full Text PDFChem Asian J
January 2025
Jilin University, Department of Chemistry, 2699 Qianjin Street, 130012, Changchun, CHINA.
Flexible covalent organic frameworks (COFs) offer distinct advantages in elasticity and adaptability over rigid COFs, but these benefits often come at the expense of crystallinity due to challenges in polymerization, complicating both synthesis and structural characterization. Current research primarily employs single flexible monomers, which limits the tunability of these frameworks. In this study, we introduce two highly crystalline, flexible COFs, ZCST-102 and ZCST-103, constructed from dual flexible monomers.
View Article and Find Full Text PDFACS Macro Lett
January 2025
School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Shanghai Jiao Tong University, Shanghai 200240, P. R. China.
Stimuli-responsive polymers have demonstrated significant potential in the development of smart materials due to their capacity to undergo targeted property changes in response to external physical or chemical stimuli. However, the scales of response in most existing stimuli-responsive polymer systems are mainly focused on three levels: functional units, chain conformations, or polymer topologies. Herein, we have developed a covalent polymer network (CPN) capable of converting into a supramolecular polymer network (SPN) within bulk materials directly at the scale of polymer network types.
View Article and Find Full Text PDFChemistry
January 2025
Nanjing University of Science and Technology, School of Chemistry and Chemical Engineering, CHINA.
Adaptiveness is an important feature for biological creatures to survive and interact with variable environments. Mechanically adaptive polymers (MAPs), which have been developed recently inspired by this adaptive nature, can regulate their mechanical properties in response to external stimuli or environmental changes. Specifically, MAPs based on dynamic chemical bonds have been synthesized and reported as an emerging material because of the intrinsic self-adaptability, outstanding mechanical properties and durable applications.
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