Reactivity studies of a corrole germanium hydride complex with aldehydes, olefins and alkyl halides.

Chem Commun (Camb)

Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, China.

Published: November 2011

The tris(pentafluorophenyl) corrole germanium hydride complex (TPFC)Ge-H was prepared by the reduction of (TPFC)Ge-OCH(3) with NaBH(4). The reactivity of (TPFC)Ge-H with series of aldehydes, olefins and alkyl halides to produce α-hydroxy alkyl and alkyl complexes was studied.

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Source
http://dx.doi.org/10.1039/c1cc15076fDOI Listing

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