We report on the performance of a system employing a multi-layer coated mirror creating circularly polarized light in a fully reflective setup. With one specially designed mirror we are able to create laser pulses with an ellipticity of more than ε = 98% over the entire spectral bandwidth from initially linearly polarized Titanium:Sapphire femtosecond laser pulses. We tested the homogeneity of the polarization with beam sizes of the order of approximately 10 cm. The damage threshold was determined to be nearly 400 times higher than for a transmissive quartz-wave plate which suggests applications in high intensity laser experiments. Another advantage of the reflective scheme is the absence of nonlinear effects changing the spectrum or the pulse-form and the scalability of coating fabrication to large aperture mirrors.
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http://dx.doi.org/10.1364/OE.19.017151 | DOI Listing |
Molecules
December 2024
School of Physics and Optoelectronics Engineering, Ludong University, Yantai 264005, China.
The substituent effect has a significant influence on the optical properties of spectral shape, width, and wavelength, and the intensities of the maximum peaks of emission (EMI) and circularly polarized luminescence (CPL). In this work, we conducted a systematic theoretical study to investigate how substituents alter the optical response in the EMI and CPL spectra of three [7]helicene derivatives at the vibronic level. To incorporate the vibronic effect, a state-of-the-art time-dependent (TD) method was used to achieve the fully converged spectra.
View Article and Find Full Text PDFPhotochem Photobiol Sci
December 2024
Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai, Miyagi, 980-8577, Japan.
The chirality and chiroptical response of materials have attracted significant attention for their potential to introduce the new science of light-matter interactions. We demonstrate that collective mode formation under modal coupling between localized surface plasmon resonances (LSPRs) with a chiral arrangement and Fabry-Pérot (FP) nanocavity modes can induce chiroptical responses. We fabricated a cluster of isotropic gold nanodisks with a chiral arrangement (gold nano-windmills, Au-NWs) on the FP nanocavities of TiO and Au film.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China.
Hetero-metal doping or substitution to create alloy clusters is a highly appealing strategy for improving physicochemical characteristics as well as tailoring optical and electronic properties, although high-yield synthesis of alloy clusters with precise positioning of doped metals is a daunting challenge. Herein, we manifest rational synthesis of chiral alloy cluster enantiomers R/S-AgCu in 85 %-87 % yield by replacing one Ag(I) atom with Cu(I) in homometallic clusters R/S-Ag, achieving circularly polarized luminescence (CPL) with a quantum yield beyond 90 %. As a small energy gap (ca.
View Article and Find Full Text PDFJ Colloid Interface Sci
March 2025
Department of Advanced Materials Engineering for Information & Electronics, Kyung Hee University, Gyeonggi-do 17104, Republic of Korea; Integrated Education Institute for Frontier Science & Technology (BK21 Four), Kyung Hee University, Gyeonggi-do 17104, Republic of Korea. Electronic address:
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November 2024
State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials, Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, P. R. China.
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