The photoionisation of propargylene and diazopropyne.

Phys Chem Chem Phys

Institute of Physical and Theoretical Chemistry, University of Würzburg, Am Hubland, D-97074 Würzburg, Germany.

Published: October 2011

The photoionisation of the C(3)H(2) isomer propargylene was studied using synchrotron radiation and coincidence techniques. An adiabatic ionisation energy (IE(ad)) of 8.99 ± 0.02 eV was determined. The precursor diazopropyne was investigated as well. Ionisation and appearance energies were measured.

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http://dx.doi.org/10.1039/c1cp22265aDOI Listing

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