A PbS-sensitized photovoltaic photodetector responsive to near-infrared (NIR) light was fabricated by depositing monolayered PbS nanoparticles on a mesoporous TiO(2) (mp-TiO(2)) film via the spin-assisted successive ionic layer adsorption and reaction (SILAR) method. By adjusting the size and morphology of the PbS nanoparticles through repeated spin-assisted SILAR cycles, the PbS-sensitized photovoltaic photodetector achieved an external quantum efficiency of 9.3% at 1140 nm wavelength and could process signals up to 1 kHz.
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http://dx.doi.org/10.1088/0957-4484/22/39/395502 | DOI Listing |
Lead sulfide (PbS) quantum dots (QDs) have been synthesized via successive ionic layer adsorption and reaction (SILAR) on a titanium dioxide (TiO2) nanoporous film for the fabrication of quantum dot-sensitized solar cells (QDSCs). The reaction is environmental friendly and energy saving. The green synthesized PbS QDs match the maximum remittance region of the solar spectrum and are suitable as sensitizers for TiO2 electrodes for cell devices application.
View Article and Find Full Text PDFNanoscale Res Lett
February 2013
School of Physics, State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100, People's Republic of China.
Narrow bandgap PbS nanoparticles, which may expand the light absorption range to the near-infrared region, were deposited on TiO2 nanorod arrays by successive ionic layer adsorption and reaction method to make a photoanode for quantum dot-sensitized solar cells (QDSCs). The thicknesses of PbS nanoparticles were optimized to enhance the photovoltaic performance of PbS QDSCs. A uniform CdS layer was directly coated on previously grown PbS-TiO2 photoanode to protect the PbS from the chemical attack of polysulfide electrolytes.
View Article and Find Full Text PDFNanotechnology
September 2011
KRICT-EPFL Global Research Laboratory, Advanced Materials Division, Korea Research Institute of Chemical Technology, Yuseong, Daejeon, Republic of Korea.
A PbS-sensitized photovoltaic photodetector responsive to near-infrared (NIR) light was fabricated by depositing monolayered PbS nanoparticles on a mesoporous TiO(2) (mp-TiO(2)) film via the spin-assisted successive ionic layer adsorption and reaction (SILAR) method. By adjusting the size and morphology of the PbS nanoparticles through repeated spin-assisted SILAR cycles, the PbS-sensitized photovoltaic photodetector achieved an external quantum efficiency of 9.3% at 1140 nm wavelength and could process signals up to 1 kHz.
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