Graphene has been grown on Cu at elevated temperatures with different carbon sources (gaseous hydrocarbons and solids such as polymers); however the detailed chemistry occurring at the Cu surface is not yet known. Here, we explored the possibility of obtaining graphene using amorphous-carbon thin films, without and with hydrogen gas added. Graphene is formed only in the presence of H(2)(g), which strongly suggests that gaseous hydrocarbons and/or their intermediates are what yield graphene on Cu through the reaction of H(2)(g) and the amorphous carbon. The large area, uniform monolayer graphene obtained had electron and hole mobilities of 2520 and 2050 cm(2) V(-1) s(-1), respectively.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/nn202802x | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Unraveling the Meaning of Effective Uptake Coefficients in Multiphase and Aerosol Chemistry.
Acc Chem Res
January 2025
Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.
ConspectusReactions of gas phase molecules with surfaces play key roles in atmospheric and environmental chemistry. Reactive uptake coefficients (γ), the fraction of gas-surface collisions that yield a reaction, are used to quantify the kinetics in these heterogeneous and multiphase systems. Unlike rate coefficients for homogeneous gas- or liquid-phase reactions, uptake coefficients are system- and observation-dependent quantities that depend upon a multitude of underlying elementary steps.
View Article and Find Full Text PDFAn azide-based sampler for monitoring abiotic reduction of chlorinated solvent contaminants in groundwater.
Chemosphere
January 2025
Department of Civil and Environmental Engineering, University of Massachusetts Lowell, Massachusetts, United States. Electronic address:
There is significant interest in monitoring abiotic decomposition of chlorinated solvents at contaminated sites due to large uncertainties regarding the rates of abiotic attenuation of trichloroethylene (TCE) and perchloroethylene (PCE) under field conditions. In this study, an innovative passive sampling tool was developed to quantify acetylene, a characteristic product of abiotic reduction of TCE or PCE, in groundwater. The sampling mechanism is based on the highly specific and facile click reaction between acetylene and an azide compound to form a biologically and chemically stable triazole product.
View Article and Find Full Text PDFImpact of trace metal supplementation on anaerobic biological methanation under hydrogen and carbon dioxide starvation.
NPJ Biofilms Microbiomes
January 2025
Department of Biology, University of Padua, via U. Bassi 58/b, 35131, Padova, Italy.
Biomethanation is a crucial process occurring in natural and engineered systems which can reduce carbon dioxide to methane impacting the global carbon cycle. However, little is known about the effect of on-and-off gaseous provision and micronutrients on bioconversion. Here, anaerobic microbiomes underwent intermittent feeding with incremental starvations and selective metal supplementation to assess the impact of hydrogen and carbon dioxide availability on microbial physiology.
View Article and Find Full Text PDFExperimental and kinetic modeling study of oxidative degradation of benzene and phenol in supercritical water.
J Environ Manage
January 2025
Shaanxi Key Laboratory of New Transportation Energy and Automotive Energy Saving, School of Energy and Electrical Engineering, Chang'an University, Xi'an, Shaanxi, 710064, PR China.
Benzene and phenol are representative aromatic compounds existing commonly in wastewater. The kinetics of oxidative degradation of benzene and phenol in supercritical water have been investigated in a flow reactor at 823 K and 250 atm, with the excess oxygen ratio ranging from 0.5 to 2.
View Article and Find Full Text PDFGuadua angustifolia biochar/TiO composite and biochar as bio-based materials with environmental and agricultural application.
Sci Rep
January 2025
Laboratorio de Microbiología Ambiental y Suelos, Unidad de Investigaciones Agropecuarias (UNIDIA), Departamento de Microbiología, Facultad de Ciencias, Pontificia Universidad Javeriana, P.O. Box 110‑23, Bogotá, DC, Colombia.
Globally, the companies that make commercial use of bamboo culms produce different kinds of solid waste rich in lignocellulosic biomass, which in some cases is not used and is discarded in landfills or incinerated in the open air; losing the possibility of recovering them and using them in other productive sectors. The research objective were to produce a biochar from Guadua agustifolia Kunth sawdust, evaluate its potential environmental and agricultural use, obtain a biochar/TiO composite to inactivate Escherichia coli and use the biochar as a soil conditioner in medicinal plants producing phenolic compounds and flavonoids. Biochar composite (produced at 300 °C for 1 h) involved TiO at 450 °C for 1 h for inactivation of E.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!