Dynamically modulating the surface plasmon resonance of doped semiconductor nanocrystals.

Nano Lett

The Molecular Foundry, Lawrence Berkeley National Laboratory , Berkeley, California 94720, United States.

Published: October 2011

Localized surface plasmon absorption features arise at high doping levels in semiconductor nanocrystals, appearing in the near-infrared range. Here we show that the surface plasmons of tin-doped indium oxide nanocrystal films can be dynamically and reversibly tuned by postsynthetic electrochemical modulation of the electron concentration. Without ion intercalation and the associated material degradation, we induce a > 1200 nm shift in the plasmon wavelength and a factor of nearly three change in the carrier density.

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http://dx.doi.org/10.1021/nl202597nDOI Listing

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