Novel synthesis of bifunctional catalysts with different microenvironments.

Chem Commun (Camb)

Toyota Central R&D Laboratories Inc., Nagakute, Aichi, 480-1191, Japan.

Published: October 2011

Acid-base bifunctional activity governed by -NH(2) group's microenvironment is evident from two different catalysts scrutinized by interchanging the location of -SO(3)H/NH(2) groups on periodic mesoporous ethylenesilica. The hydrophobic local environment plays a significant role in one-pot deacetalization/nitroaldol condensation.

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Source
http://dx.doi.org/10.1039/c1cc13825aDOI Listing

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