The title compound, C(13)H(12)ClN(3)O, exhibits a trans geometry about the N=N double bond in the solid state. The dihedral angle between the rings is 22.20 (8)°. Inter-molecular N-H⋯O hydrogen bonds between the amine and meth-oxy groups lead to the formation of a chain-like polymer along the c axis with a C(6) graph set. There is also weak non-classical C-H⋯N hydrogen bonds involving an aromatic C-H group and a diazenyl N atom, which connect the chains into a two-dimensional framework.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152038PMC
http://dx.doi.org/10.1107/S160053681102472XDOI Listing

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