A PHP Error was encountered

Severity: Warning

Message: file_get_contents(https://...@pubfacts.com&api_key=b8daa3ad693db53b1410957c26c9a51b4908&a=1): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests

Filename: helpers/my_audit_helper.php

Line Number: 176

Backtrace:

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 176
Function: file_get_contents

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 250
Function: simplexml_load_file_from_url

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3122
Function: getPubMedXML

File: /var/www/html/application/controllers/Detail.php
Line: 575
Function: pubMedSearch_Global

File: /var/www/html/application/controllers/Detail.php
Line: 489
Function: pubMedGetRelatedKeyword

File: /var/www/html/index.php
Line: 316
Function: require_once

6-Chloro-4-(4-methyl-phen-oxy-meth-yl)-2H-chromen-2-one. | LitMetric

In the title compound, C(17)H(13)ClO(3), the coumarin and phen-oxy moieties are essentially co-planar, making a dihedral angle of 1.99 (7)°. The phen-oxy moiety is oriented anti-periplanar with respect to the coumarin ring as indicated by the C-C-O-C angle of -179.97 (16)°. In the crystal, the sheet-like packing is stabilized by inter-molecular C-H⋯O and C-H⋯Cl hydrogen bonds.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151822PMC
http://dx.doi.org/10.1107/S1600536811019258DOI Listing

Publication Analysis

Top Keywords

6-chloro-4-4-methyl-phen-oxy-meth-yl-2h-chromen-2-one title
4
title compound
4
compound c17h13clo3
4
c17h13clo3 coumarin
4
coumarin phen-oxy
4
phen-oxy moieties
4
moieties essentially
4
essentially co-planar
4
co-planar making
4
making dihedral
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!