AI Article Synopsis
- The Sn(IV) atom in the compound is coordinated by a complex ligand and two methyl groups, creating a unique five-coordinate structure.
- The shape of this coordination is a mix between trigonal-bipyramidal and square-pyramidal geometries.
- In the crystal structure, there are zigzag chains formed by hydrogen bonding, along with weak interactions that help maintain the arrangement of molecules.
Article Abstract
The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(17)H(14)N(2)O(3))], is five-coordinated within a C(2)N(2)O donor set provided by the N,N,O-tridentate ligand and two methyl groups. The resultant coordination geometry is inter-mediate between trigonal-bipyramidal and square-pyramidal. In the crystal, supra-molecular zigzag chains propagating along the c- axis direction are mediated by O-H⋯O hydrogen bonds, and weak C-H⋯π inter-actions consolidate the packing.
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Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151873 | PMC |
| http://dx.doi.org/10.1107/S1600536811023506 | DOI Listing |
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