In the title salt, [C(6)H(5)N(CH(3))(3)][Sn(2)Br(5)(C(7)H(6)Br)(4)], the Sn(IV) atoms of the dinuclear anion are bridged by a Br atom; the Sn-Br(bridge) bond lengths are 2.9818 (5) and 3.0470 (5) Å. Both Sn atoms show a distorted cis-trigonal-bipyramidal coordination geometry that is distorted towards a square pyramid. In the crystal, weak C-H⋯π inter-actions occur between anions and cations.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151895 | PMC |
| http://dx.doi.org/10.1107/S1600536811021295 | DOI Listing |
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