[1,2-Bis-(diisopropyl-phosphan-yl)ethane-κP,P']dichloridonickel(II).

Acta Crystallogr Sect E Struct Rep Online

Facultad de Química, Universidad Nacional Autónoma de México, México DF, 04510, Mexico.

Published: July 2011

In the crystal structure of title compound, [NiCl(2)(C(14)H(32)P(2))], the Ni(II) atom lies on a twofold rotation axis and shows a slightly distorted square-planar coordination geometry, with a dihedral angle of 10.01 (8)° between the cis-Cl-Ni-Cl and cis-P-Ni-P planes. There is no significant inter-molecular inter-action except very weak C-H⋯Cl inter-actions. The crystal studied was a racemic twin.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151871PMC
http://dx.doi.org/10.1107/S1600536811021209DOI Listing

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