Bis[4-bromo-2-(ethyl-imino-meth-yl)phenolato-κN,O]nickel(II).

Acta Crystallogr Sect E Struct Rep Online

College of Chemistry and Bioengineering, Guilin University of Technology, Key Laboratory of Non-ferrous Metal Materials and Processing Technology, Ministry of Education, Guilin 541004, People's Republic of China.

Published: July 2011

In the title complex, [Ni(C(9)H(9)BrNO)(2)], the Ni(II) ion lies on an inversion centre and is coordinated in a slightly distorted square-planar geometry by two N atoms and two O atoms from two symmetry-related bidentate 4-bromo-2-(ethyl-imino-meth-yl)phenolate ligands. The complex forms a one-dimensional chain in the crystal structure through short C-H⋯Br contacts (H⋯Br = 3.009 Å).

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151835PMC
http://dx.doi.org/10.1107/S1600536811020885DOI Listing

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