The title compouand {[Zn(C(4)H(4)O(6))(C(12)H(8)N(2))]·6H(2)O}(n), has a linear chain structure parallel to [100] with Zn(C(4)H(4)O(6))(C(12)H(8)N(2)) repeat units; the asymmetric unit consists of one Zn(2+) cation, one l-tartrate dianion, one 1,10-phenanthroline and six free water mol-ecules. The Zn atom is in a distorted octa-hedral ZnN(2)O(4) coordination environment. The crystal structure is stabilized by O-H⋯O hydrogen bonds and π-π stacking of the phenanthroline units [centroid-centroid distances in the range 3.552 (2)-3.625 (2)Å] occurs between the chains. The title compound is isotypic with the Cu and Mn analogues.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3152042 | PMC |
| http://dx.doi.org/10.1107/S1600536811024780 | DOI Listing |
Publication Analysis
Top Keywords
poly[[110-phenanthrolineμ-l-tartratozinc] hexa-hydrate]
4
hexa-hydrate] title
4
title compouand
4
compouand {[znc4h4o6c12h8n2]·6h2o}n
4
{[znc4h4o6c12h8n2]·6h2o}n linear
4
linear chain
4
chain structure
4
structure parallel
4
parallel [100]
4
[100] znc4h4o6c12h8n2
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!