A novel bis-EDOT-based monomer with ethylene glycol oligomers was synthesized and shown to exhibit strong ion solvation, good transport properties, and effective charge screening. These properties greatly improved J(SC) (4.2 to 7.0 mA cm(-2)) and η (1.6 to 2.9%) in an iodine-free solid state dye-sensitized solar cell (DSSC) employing a Z-907 sensitizer, compared with the corresponding values of DSSCs fabricated using the standard bis-EDOT.
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http://dx.doi.org/10.1039/c1cc13376d | DOI Listing |
RSC Adv
September 2018
Shenzhen Key Laboratory of Laser Engineering, College of Optoelectronic Engineering, Shenzhen University Shenzhen 518060 People's Republic of China.
A flexible self-powered ultraviolet (UV) photodetector based on ZnO nanorods (NRs) and a novel iodine-free quasi solid-state electrolyte was fabricated. The obtained device has a fast and high response to UV light illumination at zero bias and also shows long-term stability. The responsivity is 50.
View Article and Find Full Text PDFChemistry
July 2016
Department of Chemistry, Indiana University Bloomington, 800 E. Kirkwood Avenue, Bloomington, Indiana, 47405, USA.
Human insulin-like peptide-6 (INSL-6) belongs to the insulin superfamily and shares the distinctive disulfide bond configuration of human insulin. In this report we present the first chemical synthesis of INSL-6 utilizing fluorenylmethyloxycarbonyl-based (Fmoc) solid-phase peptide chemistry and regioselective disulfide bond construction protocols. Due to the presence of an oxidation-sensitive tryptophan residue, two new orthogonal synthetic methodologies were developed.
View Article and Find Full Text PDFACS Appl Mater Interfaces
June 2015
Department of Chemical Engineering, Pohang University of Science and Technology, San31, Nam-gu, Pohang, Kyoungbuk 790-780, Korea.
We synthesized thiophene-based monomers (bis-EDOTs) with different ethylene glycol oligomer (EGO) lengths (TBO3, TBO4, and TBO5) and investigated their polymerization characteristics during photoelectrochemical polymerization (PEP) at the surfaces of dye (D205)-sensitized TiO2 nanocrystalline particles. During the PEP reaction, monomers were expected to diffuse toward neighboring dyes through the growing polymer layers to enable continuous chain growth. We found that the less bulky monomer (TBO3) formed a more compact polymer layer with a high molecular weight.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
July 2012
Department of Chemical and Biomolecular Engineering, Yonsei University, Seodaemun-gu, Seoul, Korea.
Nanopatterning provides facile process to well-arrayed mesoporous inorganic oxide films at low cost by using readily available pastes and elastomeric nanostamps. The fabricated nanopattern boosted the light-harvesting efficiency of dye-sensitized solar cells (DSSCs) by a light-trapping technique. The iodine-free solid-state DSSCs showed a 40 % increase in the current density and high efficiency (7.
View Article and Find Full Text PDFChem Commun (Camb)
October 2011
Department of Chemical Engineering, Pohang University of Science and Technology, San 31, Nam-gu, Pohang, Kyoungbuk, Korea.
A novel bis-EDOT-based monomer with ethylene glycol oligomers was synthesized and shown to exhibit strong ion solvation, good transport properties, and effective charge screening. These properties greatly improved J(SC) (4.2 to 7.
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