A novel technique for growing graphene on relatively inert metals, consisting in the thermal decomposition of low energy ethylene ions irradiated on hot metal surfaces in ultrahigh vacuum, is reported. By this route, we have grown graphene monolayers on Cu(111) and, for the first time, on Au(111) surfaces. For both noble metal substrates, but particularly for Au(111), our scanning tunneling microscopy and spectroscopy measurements provide sound evidence of a very weak graphene-metal interaction.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1021/nl201281m | DOI Listing |
Molecules
January 2025
College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China.
Daytime radiative cooling, based on selective infrared emissions through atmospheric transparency windows to outer space and the reflection of solar irradiance, is a zero-energy and environmentally friendly cooling technology. Poly(ethylene oxide) (PEO) electrospun membranes have both selective mid-infrared emissions and effective sunlight reflection, inducing excellent daytime radiative cooling performance. However, PEO is highly water soluble, which makes electrospun PEO membranes unable to cope with rainy conditions when used for outdoor daytime radiative cooling.
View Article and Find Full Text PDFInorg Chem
January 2025
College of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou 363000, China.
Upcycling organic and inorganic waste into value-added metal-organic frameworks (MOFs) presents a sustainable strategy for mitigating waste pollution and promoting economic viability. However, rapid synthesis of MOF materials derived from actual industrial waste under mild conditions remains challenging. Herein, Fe-MOF MIL-88B(Fe) was successfully fabricated within 1 h at room temperature using galvanizing pickling waste liquid and terephthalic acid derived from waste poly(ethylene terephthalate).
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Northwest University, College of Chemistry & Materials Science, CHINA.
The encapsulation of viologen derivatives in metal-organic frameworks (MOFs) to construct host-guest materials has been widely discussed owing to their distinctive spatial arrangement and physical/chemical properties. Herein, three new photochromic MOFs (NWM-1-3) have been successfully synthesized by 1,1,2,2-Tetra(4-carboxylphenyl)ethylene (H4TCPE) ligand as well as three different viologen derivatives based on host-guest strategy. Remarkably, NWM-1-3 exhibit a notable reversible photochromism change from yellow to green under 365 nm UV irradiation.
View Article and Find Full Text PDFFood Chem X
January 2025
College of Horticulture, Hebei Agricultural University, Baoding 071001, China.
Few studies have explored the impact of blue light-emitting diode (BL) irradiation combined with different storage temperatures on antioxidant defense and cell wall metabolic activities related to the quality deterioration of postharvest strawberries. This study investigates the effects of BL exposure as a non-chemical preservation strategy to improve the postharvest quality of strawberries stored at 22 °C and 8 °C. Over a 10-day storage period, BL irradiation significantly reduced respiratory and ethylene production rates, while preserving fruit firmness and increasing the contents of soluble sugar and total phenol at both temperatures.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
Hubei Three Gorges Laboratory, Yichang 443000, China.
A series of flexible polyacrylonitrile/TiO (PAN/P25) multi-porous nanotubular membranes were successfully constructed by facile electrospinning combined with an ethylene glycol solvothermal induce strategy. The effects of P25 dosage and solvothermal time on the morphology of samples were systematically investigated, which were characterized in terms of surface morphology, microstructure, specific surface area, thermal analysis, wettability, photoelectrochemical and fluorescence spectra. Rhodamine B (RhB) and () were employed as simulated pollutants to evaluate photocatalytic degradation and antibacterial properties of the PAN/P25-3 multi-porous nanotubular membrane.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!