https://eutils.ncbi.nlm.nih.gov/entrez/eutils/efetch.fcgi?db=pubmed&id=21819063&retmode=xml&tool=Litmetric&email=readroberts32@gmail.com&api_key=61f08fa0b96a73de8c900d749fcb997acc09 218190632011122120110831
1520-5126133352011Sep07Journal of the American Chemical SocietyJ Am Chem SocAdditive-free clicking for polymer functionalization and coupling by tetrazine-norbornene chemistry.138281383113828-3110.1021/ja203957hHerein we report the use of a tetrazine-norbornene inverse electron demand Diels-Alder conjugation applied to polymer end-functionalization and polymer-polymer coupling. The reaction was found to be applicable to polymer-polymer coupling, as judged by SEC, DOSY NMR, and LCxSEC analyses, giving diblock copolymers by merely mixing the constituent homopolymers together under ambient conditions, using no catalyst, additive, or external stimulus.HansellClaire FCFDepartment of Chemistry, University of Warwick, Coventry, UK.EspeelPieterPStamenovićMilan MMMBarkerIan AIADoveAndrew PAPDu PrezFilip EFEO'ReillyRachel KRKengJournal Article20110811
United StatesJ Am Chem Soc75030560002-7863
201189602011896020118961ppublish2181906310.1021/ja203957h