Experimental investigation of electronic states of LiCs dissociating to Li(2(2)S) and Cs(5(2)D) atoms.

Polarization labeling spectroscopy technique was used to measure excitation spectra of LiCs molecule in the spectral range of 16,000-18,500 cm(-1). Four band systems were observed and assigned to transitions from the ground X(1)Σ(+) state to excited states (4)Ω = 0(+), (5)Ω = 0(+), (5)Ω = 1, and (6)Ω = 1 (in Hund's case (c) notation proper here), the latter three states being fine structure components of the states d(3)Π and e(3)Σ(+), nominally of triplet symmetry. The observed states are characterized spectroscopically and the experimental results are compared with predictions of theoretical calculations, showing accuracy of the theoretical electronic term values better than 100 cm(-1) and of the ω(e) and R(e) constants within 5%.