The submersion of sodium clusters in helium nanodroplets: identification of the surface → interior transition.

J Chem Phys

Institut für Ionenphysik und Angewandte Physik und Research Platform Advanced Materials, Universität Innsbruck, Technikerstr. 25, A-6020 Innsbruck, Austria.

Published: July 2011

AI Article Synopsis

  • The study confirms a theoretical prediction regarding the submersion of sodium clusters in helium nanodroplets, showing a transition from surface location to full immersion as cluster size increases.
  • It identifies the specific electron energy threshold needed for ionizing larger Na(n) clusters, contributing to our understanding of their behavior in helium environments.
  • The research establishes that a minimum cluster size of 21 atoms is necessary for full submersion, aligning with previous theoretical findings.

Article Abstract

The submersion of sodium clusters beyond a critical size in helium nanodroplets, which has recently been predicted on theoretical grounds, is demonstrated for the first time. Confirmation of a clear transition from a surface location, which occurs for alkali atoms and small clusters, to full immersion for larger clusters, is provided by identifying the threshold electron energy required to initiate Na(n) cluster ionization. On the basis of these measurements, a lower limit for the cluster size required for submersion, n ≥ 21, has been determined. This finding is consistent with the recent theoretical prediction.

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http://dx.doi.org/10.1063/1.3610388DOI Listing

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