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Gold-catalyzed propargylic substitutions: Scope and synthetic developments. | LitMetric
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Gold-catalyzed propargylic substitutions: Scope and synthetic developments.

Olivier Debleds Eric Gayon Emmanuel Vrancken Jean-Marc Campagne

Beilstein J Org Chem

Institut Charles Gerhardt, UMR 5253, Equipe AM2N, ENSCM 8 rue de l'Ecole Normale, 34296 Montpellier Cédex, France.

Published: November 2011

This personal account summarizes our recent developments in gold-catalyzed direct substitutions on propargylic (allylic, benzylic) alcohols, with various nucleophiles (and bi-nucleophiles) based on the σ- and/or π-acidity of gold(III) complexes. Synthetic developments are also briefly described.

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 Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3135077PMC
http://dx.doi.org/10.3762/bjoc.7.99DOI Listing

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