The low-temperature absorption and excitation spectra of interconfigurational 4f-5d transitions of Tb(3+) in a cubic fluoride host demonstrate the appearance of a first-order linear Jahn-Teller effect for the high-spin excited states of the excited electronic configuration 4f(7)5d involving 5d t(2g) orbitals. The τ(2g) mode is observed to be responsible for the splitting of the otherwise degenerate 5d t(2g) orbitals.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/jp205011v | DOI Listing |
Publication Analysis
Top Keywords
4f-5d transitions
8
transitions tb3+
8
t2g orbitals
8
tb3+ cs2nayf6
4
cs2nayf6 distortion
4
distortion excited-state
4
excited-state configuration
4
configuration low-temperature
4
low-temperature absorption
4
absorption excitation
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!