Historically, the synthesis of perbromate ion through conventional oxidation routes has proven elusive. Herein, we report perbromate ion formation through the reaction of hypobromite and bromate ions in an alkaline sodium hypobromite solution. Formation was established via LC-MS/MS analysis of the bromate and perbromate ions in the reaction solutions over a 13-day period. Furthermore, it was discovered that the perbromate ion was also formed as a result of the electrospray ionization process. Selective reduction of the bromate ion prior to analysis was used to confirm the two formation pathways.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/ic201329q | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Two new methods of synthesis for the perbromate ion: chemistry and determination by LC-MS/MS.
Inorg Chem
September 2011
Southern Nevada Water Authority, Applied Research & Development Center, P.O. Box 99954, Las Vegas, Nevada 89193, USA.
Historically, the synthesis of perbromate ion through conventional oxidation routes has proven elusive. Herein, we report perbromate ion formation through the reaction of hypobromite and bromate ions in an alkaline sodium hypobromite solution. Formation was established via LC-MS/MS analysis of the bromate and perbromate ions in the reaction solutions over a 13-day period.
View Article and Find Full Text PDFDiphenyl(dipyrazolyl)methane complexes of Ni: synthesis, structural characterization, and chromotropism of NiBr2 derivatives.
Inorg Chem
September 2007
Département de Chimie, Université de Montréal, C. P. 6128, Succursale Centre-ville, Montréal, Québec, Canada H3C 3J7.
The reaction of NiBr2 with the bidentate ligand diphenyl(dipyrazolyl)methane (dpdpm) gives the pentacoordinated complexes [(dpdpm)Ni(mu-Br)Br]2 (1), [(dpdpm)NiBr2(H2O)] (2a), and [(dpdpm)NiBr(H2O)2]Br (2b), or the octahedral complexes [(dpdpm)NiBr(H2O)2(CH3CN)]Br (3), [(dpdpm)2NiBr2] (4), and [(dpdpm)2NiBr(H2O)]Br (5). All of these complexes are paramagnetic, both in the solid state and in solution, and have been characterized by spectroscopic (IR, NMR, and UV-vis-NIR) and X-ray diffraction studies. The unoccupied coordination site in the pentacoordinated compounds allows long-range interactions, in the solid state, between the Ni center and a Ph substituent of the dpdpm ligand.
View Article and Find Full Text PDFLithium perbromate monohydrate at 296 and 173 K.
Acta Crystallogr C
January 1995
Department of Chemistry, Ohio State University, Columbus 43210.
Lithium tetraoxobromate(1-) monohydrate, LiBrO4.-H2O, whose perchlorate analog has not yet been described, is found to be isomorphic with NaBrO4.H2O and NaClO4.
View Article and Find Full Text PDFStructure of tetraaquacalcium perbromate.
Acta Crystallogr C
August 1993
Department of Chemistry, Ohio State University, Columbus 43210.
The structure of the title compound consists of columns of Ca ions surrounded by four columns of perbromate ions and four columns of water molecules alternating in pairs. The CaO8 complex was found to be dimensionally similar to corresponding complexes in other simple tetrahydrated calcium salts. The eight coordinating O atoms form a polyhedron which departs only slightly from a (distorted) square antiprism.
View Article and Find Full Text PDFStructure of sodium perbromate monohydrate.
Acta Crystallogr C
March 1992
Department of Chemistry, Ohio State University, Columbus 43210.
NaBrO4.H2O, Mr = 184.90, monoclinic, C2/c, a = 15.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!