A noble electrode for capacitive deionization (CDI) was prepared by embedding ion exchanger onto the surface of a carbon electrode to practice membrane capacitive deionization (MCDI). Bromomethylated poly (2, 6-dimethyl-1, 4-phenylene oxide) (BPPO) was sprayed on carbon cloth followed by sulfonation and amination to form cation exchange and anion exchange layers, respectively. The ion exchange layers were examined by Scanning electron microscopy (SEM) and Fourier transform infrared spectrometer (FT-IR). The SEM image showed that the woven carbon cloth was well coated and connected with BPPO. The FT-IR spectrum revealed that sulfonic and amine functional groups were attached on the cationexchange and anionexchange electrodes, respectively. The advantages of the developed carbon electrodes have been successively demonstrated in a batch and a continuous mode CDI operations without ion exchange membranes for salt removal using 100 mg/L NaCl solution.
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http://dx.doi.org/10.1016/j.watres.2011.06.028 | DOI Listing |
Environ Sci Technol
December 2024
Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials, State Environmental Protection Key Laboratory of Integrated Surface Water-Groundwater Pollution Control, Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution Control, SUSTech Energy Institute for Carbon Neutrality, School of Environmental Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, China.
Seawater desalination via electrochemical battery deionization (BDI) has shown significant potential for freshwater production. However, its widespread application has been limited by the high energy costs involved. To facilitate the commercialization of BDI technology, it is crucial to develop innovative integrated BDI systems that utilize sustainable energy sources and assess their practical performance for desalination of natural seawater.
View Article and Find Full Text PDFJ Hazard Mater
December 2024
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, PR China; Science Island Branch of Graduate School, University of Science and Technology of China, Hefei 230026, PR China. Electronic address:
Recently, hybrid capacitive deionization (HCDI) has garnered significant attention for its potential in the selective extraction of cesium (Cs) from radioactive wastewater and salt lakes, which is crucial for resolving the supply-demand imbalance of cesium resources and eliminating radioactive contamination. However, developing HCDI electrodes capable of effectively separating and extracting Cs remains a significant challenge. In this work, we proposed an innovative strategy involving the doping of inactive metal ions to develop zinc-doped manganese hexacyanoferrate (ZMFC) as an HCDI cathode.
View Article and Find Full Text PDFChimia (Aarau)
December 2024
College of Science and Engineering, Hamad Bin Khalifa University, P.O. Box: 34110, Doha, Qatar.
Demand for lithium is expected to quadruple by the end of the decade. Without new sources of production, the supply-demand curve is expected to invert. Traditional geological reserves will not be able to meet the anticipated gap, thus unconventional sources of lithium will need to be utilized, setting the stage for fierce competition for perhaps the most critical of mineral resources required for the energy transition.
View Article and Find Full Text PDFSmall
December 2024
Key Laboratory of Catalytic Conversion and Clean Energy in Universities of Shandong Province, College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, Shandong, 273165, P. R. China.
Nanostructured Faradaic materials show extraordinary promise for capacitive deionization (CDI) toward the relief of global freshwater scarcity. But at present, there exist at least two shortages for the development of CDI electrode materials. In laboratory studies, evaluating their desalination performance is usually based on low mass loadings (<1 mg cm), which is far behind the practical demand for fabricating high-mass-loading CDI electrodes or devices.
View Article and Find Full Text PDFChem Commun (Camb)
December 2024
College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, P. R. China.
Removing Cu from wastewater through capacitive deionization at low temperatures is a great challenge. Herein, a new strategy for enhancing the performance was developed using photothermal carbon nanospheres as the electrodes. Upon irradiating with sunlight, the Cu removal rate and Cu/Na selectivity were increased by 74% and 43%, respectively.
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