A room temperature process for the production of crystalline hematite Fe2O3 nanoparticles with an indirect band gap of 2 eV and size range from 15 to 35 nm is presented. The material to have an optical band gap of 2 eV as determined by the Tauc relationship which makes it suitable for visible light photocatalysis. The XRD pattern of the material shows no secondary phases to be present for the low temperature processed material.
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http://dx.doi.org/10.1166/jnn.2011.3757 | DOI Listing |
Background: Except host and environmental factors influencing individual human cytokine responses, pre-analytical handling procedures and detection methods also affect cytokine levels.
Methods: In this study, we used cytometric bead array (CBA) and chemiluminescence (ECL). These two methods were used to test serum and plasma samples from 50 healthy adult volunteers and 50 rheumatoid arthritis (RA) patients' cytokine levels.
Inorg Chem
January 2025
Institute for Inorganic Chemistry and Center for Sustainable Systems Design (CSSD), Paderborn University, Paderborn 33098, Germany.
A series of Co complexes [Co(ImP)][PF], with HImP = 1,1'-(1,3-phenylene)bis(3-methyl-1-imidazole-2-ylidene)) and R = Me, Et, Pr, Bu, is presented in this work. The influence of the strong donor ligand on the ground and excited-state photophysical properties was investigated in the context of different alkyl substituents at the imidazole nitrogen. X-ray diffraction revealed no significant alterations of the structures and all differences in the series emerge from the electronic structures.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Harvard University, Rowland Institute at Harvard, 02138, Cambridge, UNITED STATES OF AMERICA.
The dynamic response of heterogeneous catalytic materials to their environment opens a wide variety of possible surface states which may have increased catalytic activity. In this work, we find that it is possible to generate a surface state with increased catalytic activity over metallic 2nm Pt nanoparticles by performing a thermal treatment of the CO*-covered Pt catalyst. This state is characterised by its ability to oxidise CO to CO2 at room temperature.
View Article and Find Full Text PDFSmall
January 2025
Institute of Fundamental Technological Research, Polish Academy of Sciences, Pawinskiego 5B Str., Warsaw, 02-106, Poland.
The urea oxidation reaction (UOR) is characterized by a lower overpotential compared to the oxygen evolution reaction (OER) during electrolysis, which facilitates the hydrogen evolution reaction (HER) at the cathode. Charge distribution, which can be modulated by the introduction of a heterostructure, plays a key role in enhancing the adsorption and cleavage of chemical groups within urea molecules. Herein, a facile all-room temperature synthesis of functional heterojunction NiCoS/CoMoS grown on carbon cloth (CC) is presented, and the as-prepared electrode served as a catalyst for simultaneous hydrogen evolution and urea oxidation reaction.
View Article and Find Full Text PDFJ Org Chem
January 2025
Department of Chemistry, Ludwig-Maximilian University of Munich (LMU), 81377 Munich, Germany.
Cyanoacetylene and dicyanoacetylene react in the ternary methylation system CHF/SbF/SO under the formation of its corresponding -monomethylated and -dimethylated species, respectively. Additionally, in the case of dicyanoacetylene, an -dimethylated HF-addition product was obtained. The salts were characterized by low-temperature vibrational spectroscopy.
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