AI Article Synopsis

  • The compound features a zinc atom coordinated in a square-pyramidal geometry, with four oxygen atoms from acetyl-acetonate ligands forming the base and a nitrogen atom from pyridine at the top.
  • The crystal structure exhibits a hydrogen-bonded ribbon arrangement formed by C-H⋯O interactions, which runs parallel to a specific crystallographic direction.
  • Overall, the structure highlights the unique coordination behavior of zinc in conjunction with organic ligands and their role in crystal packing.

Article Abstract

In the title compound, [Zn(C(5)H(7)O(2))(2)(C(5)H(5)N)], the metal atom has square-pyramidal coordination geometry with the basal plane defined by the four O atoms of the chelating acetyl-acetonate ligands and with the axial position occupied by the pyridine N atom. The crystal packing is characterized by a C-H⋯O hydrogen-bonded ribbon structure approximately parallel to [10[Formula: see text]].

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120430PMC
http://dx.doi.org/10.1107/S1600536811019854DOI Listing

Publication Analysis

Top Keywords

bisacetyl-acetonato-κoo'pyridine-κnzincii title
4
title compound
4
compound [znc5h7o22c5h5n]
4
[znc5h7o22c5h5n] metal
4
metal atom
4
atom square-pyramidal
4
square-pyramidal coordination
4
coordination geometry
4
geometry basal
4
basal plane
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!