The polymeric title compound, [Ce(C(7)H(3)N(2)O(6))(3)(C(2)H(6)OS)(2)](n), exists as a linear chain along [111] as the three dinitro-benzoate anions each engages in bridging adjacent dimethyl sulfoxide (DMSO) coordinated Ce(III) atoms. The metal atoms are surrounded by eight O atoms in a square-anti-prismatic environment. There are two independent formula units in the asymmetric unit. The S atoms of two of the four DMSO mol-ecules are disordered in a 0.926 (3):0.074 (3) ratio.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120519 | PMC |
| http://dx.doi.org/10.1107/S1600536811015947 | DOI Listing |
Publication Analysis
Top Keywords
catena-poly[[bis-dimethyl sulfoxide-κoceriumiii]tris-μ2-35-dinitro-benzoato-κoo']
4
sulfoxide-κoceriumiii]tris-μ2-35-dinitro-benzoato-κoo'] polymeric
4
polymeric title
4
title compound
4
compound [cec7h3n2o63c2h6os2]n
4
[cec7h3n2o63c2h6os2]n exists
4
exists linear
4
linear chain
4
chain [111]
4
[111] three
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!